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21.
Tetsutaro Kimachi Eri Torii Rina Ishimoto Ayako Sakue Motoharu Ju-ichi 《Tetrahedron: Asymmetry》2009,20(14):1683-1689
Starting from a reduced lapachol compound, the total synthesis of rhinacanthin A in both racemic and enantioenriched forms is achieved in eight steps without forming any undesired β-lapachone derivatives. For the synthesis of enantioenriched rhinacanthin A, the introduction of the asymmetric center was carried out by using the catalytic asymmetric epoxidation of an unfunctional trisubstituted olefin using Shi’s epoxidation diketal catalyst. The acidic treatment of a derived enantioenriched epoxynaphthol and the following CAN oxidation afforded the target molecule with high enantiomeric purity. 相似文献
22.
Xiao-Ming Ren Guang-Xiang Liu Heng Xu Tomoyuki Akutagawa Takayoshi Nakamura 《Polyhedron》2009,28(9-10):2075-2079
A nonmagnetic compound, [NO2BzPy][Cu(mnt)2] (mnt2? = maleonitriledithiolate; NO2BzPy+ = 1-(4′-nitrobenzyl)pyridinium), is isostructural with [NO2BzPy][Ni(mnt)2], which is a quasi-1D spin system and exhibits a spin-Peierls-like transition with J = 192 K in the gapless state and spin energy gap = 738 K in the dimerization state, respectively. Further, five nonmagnetic impurity doped compounds [NO2BzPy][CuxNi1?x(mnt)2] (x = 0.04–0.74) were prepared, and their crystal structures as well as magnetic properties were investigated. The nonmagnetic doping causes the suppression of the spin transition with an average rate of 139(13) K/percentage of dopant concentration, and the transition collapse is estimated at around x > 0.5. 相似文献
23.
Tomohiro Narukawa Takayoshi Kuroiwa Izumi Narushima Koichi Chiba 《Analytical sciences》2008,24(3):355-360
The sensitivity of graphite furnace atomic absorption spectrometry (GFAAS) to arsenobetaine (AB) was 1.3-times higher than to inorganic As. In order to understand the mechanism underlying this observation, the atomization processes for both chemical species were investigated in terms of the enthalpy change (DeltaH) during the atomization process in GFAAS. The enthalpy change of AB was slightly lower than that of inorganic As, which suggested that AB was atomized more efficiently than was inorganic As. Moreover, it was observed that some co-existing organic materials enhanced the analytical sensitivity of inorganic As. The sensitivity difference between inorganic As and AB depended upon the mechanisms of their atomization processes. 相似文献
24.
In heat transport devices such as oscillating heat pipe (OHP), dryout phenomena is very important and avoided in order to give the optimum performance. However, from the previous studies (including our studies), the dryout phenomena in OHP and its mechanism are still unclear. In our studies of OHP (Senjaya and Inoue in Appl Thermal Eng 60:251–255, 2013; Int J Heat Mass Transfer 60:816–824, 2013; Int J Heat Mass Transfer 60:825–835, 2013), we introduced the importance and roles of liquid film in the operating principle of OHP. In our previous simulation, the thickness of liquid film was assumed to be uniform along a vapor plug. Then, dryout never occurred because there was the liquid transfer from the liquid film in the cooling section to that in the heating section. In this research, the liquid film is not treated uniformly but it is meshed similarly with the vapor plugs and liquid slugs. All governing equations are also solved in each control volume of liquid film. The simulation results show that dryout occurs in the simulation without bubble generation and growth. Dryout is started in the middle of vapor plug, because the liquid supply from the left and right liquid slugs cannot reach until the liquid film in the middle of vapor plug, and propagates to the left and right sides of a vapor plug. By inserting the bubble generation and growth phenomena, dryout does not occur because the wall of heating section is always wetted during the bubble growth and the thickness of liquid film is almost constant. The effects of meshing size of liquid film and wall temperature of heating section are also investigated. The results show that the smaller meshing size, the smaller liquid transfer rate and the faster of dryout propagation. In the OHP with higher wall temperature of heating section, dryout and its propagation also occur faster. 相似文献
25.
Guo‐Qing Bian Takayoshi Kuroda‐Sowa Hisashi Konaka Masahiko Maekawa Megumu Munakata 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(7):m338-m340
The title compound, [Mn2(μ‐O)(C6H3NO3)2(C5H5N)4]·H2O, was isolated from the reaction of 2,6‐pyridinedicarboxylic acid with [Mn12O12(CH3COO)16(H2O)4] in pyridine. The dimanganese complex has twofold symmetry; the MnIII atoms are bridged by one oxo and two amidate ligands and show compressed octahedral Jahn–Teller distortion. The molecular packing comprises a three‐dimensional structure constructed by means of extensive intermolecular interactions, including three kinds of hydrogen bonds and π–π interactions. 相似文献
26.
Takayoshi Suzuki 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(4):e118-e119
The title compound [Co(C5H7O2)2(C13H13P)(CH4O)]PF6·H2O, (I), which was converted from trans‐[Co(acac)2(PMePh2)(H2O)]PF6 (acac is pentane‐2,4‐dionato) by recrystallization from aqueous methanol, has been confirmed as have a coordinated methanol ligand. The molecular structure of the complex cation, trans‐[Co(acac)2(PMePh2)(MeOH)]+, is similar to that of the above aqua complex found in the ClO4 salt [Kashiwabara et al. (1995). Bull. Chem. Soc. Jpn, 68 , 883–888]. The Co—O bond length for the coordinated methanol is 2.059 (3) Å. There is an intermolecular hydrogen bond between the OH group of the coordinated methanol and one of the O atoms of the acac ligands in an adjacent complex cation [O5?O3′ = 2.914 (4) Å], giving a centrosymmetric dimeric dicationic complex. 相似文献
27.
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29.
We show the critical Sobolev inequalities in the Besov spaces with the logarithmic form such as Brezis-Gallouet-Wainger and
Beale-Kato-Majda. As an application of those inequalities, the regularity problem under the critical condition to the Navier-Stokes
equations, the Euler equations in and the gradient flow to the harmonic map to the sphere are discussed. Namely the Serrin-Ohyama type regularity criteria
are improved in the terms of the Besov spaces.
Received: 21 September 2000; in final form: 16 Feburary 2001 / Published online: 18 January 2002 相似文献
30.
We performed selective excitations of the first- and second-excited Frenkel exciton states (Q- and B-excitons) with use of sub-40-fs and sub-5-fs visible laser pulses. The transient absorption signals exhibit oscillatory features associated with molecular vibrations. From an analysis of the spectral profiles of the phase and amplitude of the oscillation, the experimental result is well explained by the modulated transition dipole moment, which is caused by the dynamic intensity borrowing from the intense B-transition to the weak Q-transition. 相似文献